Ian
Yes connect the output directly to a DI. The 5V output on the WebBrick will power at least 2 of these along with temperature sensors. These a very low energy devices so remember to use the twisted pairs of CAT5(e) correctly; 5V/Ground and Output/Ground.
Configure the DI to use the rising edge, dwell a DO for 2-n seconds and set UDPSend to None (otherwise you'll have a chatty WebBrick).
Each PIR should have its own DI, or use a diode and resistor network to combine.
Andy
Note: WebBricks only use 50mA at 12V so they are low energy devices. Low energy low voltage systems need to use twisted pair cables properly to avoid pickup from mains devices. WBs have 20mS de-bounce timers and will filter some degree of hum. Proper installation will make them bullet-proof from RFI and induced spikes. I really should write up a separate note.