Paul
First off, its pretty rare to to the schedules in a WebBrick. They are there for stuff like green houses, i.e. applications that always run. Schedules are more commonly part of the global intelligence of a home and therefore implemented by the Gateway. That said, fair enough because we don't say much about the Gateway on the forum - but we will !
In terms of scenes, it helps to think about the type of switches you'll be using. If they have mimics, then reserve two of the digital outputs for these. 6-7 are TTL outs and therefore not so commonly used and thus make the best choice.
A single WebBrick has enough capacity for one major and one minor room and scenes can be in two banks [0-7] [8-11] Use the first bank for the major room and the second for the minor room.
Here is an example of a scene configuration.